Entropy-stabilized oxides represent a novel family of advanced ceramic materials with attractive functional properties. In this work, entropy-stabilized oxides, in the system (Mg, Co, Ni, Cu, Zn)O, were produced by co-precipitation and hydrothermal synthesis. Although TG/DTA and XRD analyses of as-synthetized powders point out complex thermal evolution, in both cases the desired single-phase rock salt solid solution was obtained after a proper thermal treatment. The dilatometric analysis points out the excellent sinterability of the obtained powders, which were successfully consolidated for the first time reaching nearly full density (~ 97%) at relatively low temperature (1050 °C).
Synthesis and sintering of (Mg, Co, Ni, Cu, Zn)O entropy-stabilized oxides obtained by wet chemical methods
Spiridigliozzi, Luca;Dell’Agli, Gianfranco;
2018-01-01
Abstract
Entropy-stabilized oxides represent a novel family of advanced ceramic materials with attractive functional properties. In this work, entropy-stabilized oxides, in the system (Mg, Co, Ni, Cu, Zn)O, were produced by co-precipitation and hydrothermal synthesis. Although TG/DTA and XRD analyses of as-synthetized powders point out complex thermal evolution, in both cases the desired single-phase rock salt solid solution was obtained after a proper thermal treatment. The dilatometric analysis points out the excellent sinterability of the obtained powders, which were successfully consolidated for the first time reaching nearly full density (~ 97%) at relatively low temperature (1050 °C).I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
