BACKGROUNDElectronic waste (e-waste) is a recent environmental problem worldwide, because it is bulky in size causing solid waste disposal problems, especially due to the release of heavy metals into the environment. On the other hand, metal scarcity is another global issue with e-waste, making it a prominent candidate for metal recovery. RESULTSDesktop computer printed circuit boards (PCBs) were evaluated as a potential source of Cu, Ni and Zn recovery using a bio-hydrometallurgical method. The process parameters for metal leaching i.e. different particle sizes, leaching agents, contact time, liquid to solid (L/S) ratio, and agitation speed were evaluated in batch systems. At the following optimal conditions of 1molL(-1) HNO3, L/S ratio of 20 with 200rpm agitation speed using 0.5-1.0mm particle size, the concentrations of Cu, Ni and Zn leached out from the PCBs were 450, 8 and 4mgg(-1) PCBs, respectively. Continuous leaching in an up-flow leaching column using the optimized parameters, coupled to sulfide precipitation yielded>90% Cu recovery (0.48gg(-1) PCBs). CONCLUSIONPCBs are a good candidate for metal recovery, especially Cu. This can be achieved by combining chemical leaching and biogenic sulfide precipitation techniques.
Effect of operational parameters on the leaching efficiency and recovery of heavy metals from computer printed circuit boards
ESPOSITO, Giovanni;
2015-01-01
Abstract
BACKGROUNDElectronic waste (e-waste) is a recent environmental problem worldwide, because it is bulky in size causing solid waste disposal problems, especially due to the release of heavy metals into the environment. On the other hand, metal scarcity is another global issue with e-waste, making it a prominent candidate for metal recovery. RESULTSDesktop computer printed circuit boards (PCBs) were evaluated as a potential source of Cu, Ni and Zn recovery using a bio-hydrometallurgical method. The process parameters for metal leaching i.e. different particle sizes, leaching agents, contact time, liquid to solid (L/S) ratio, and agitation speed were evaluated in batch systems. At the following optimal conditions of 1molL(-1) HNO3, L/S ratio of 20 with 200rpm agitation speed using 0.5-1.0mm particle size, the concentrations of Cu, Ni and Zn leached out from the PCBs were 450, 8 and 4mgg(-1) PCBs, respectively. Continuous leaching in an up-flow leaching column using the optimized parameters, coupled to sulfide precipitation yielded>90% Cu recovery (0.48gg(-1) PCBs). CONCLUSIONPCBs are a good candidate for metal recovery, especially Cu. This can be achieved by combining chemical leaching and biogenic sulfide precipitation techniques.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
